Radovan Sebesta

Stereoseelctive synthesis and asymmetric catalysis; transition metal catalysis and organometallic coumpounds; domino reactions; sustainable chemistry; mechanochemistry; asymmetric organocatalysis.

1. Organocatalyst efficiency in α-aminoxylation and α-hydrazination of carbonyl derivatives in aqueous media and ball-mill. Veverková, E.; Modrocká, V.; Šebesta, R. Eur. J. Org. Chem. 2017, 1191-1195. https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201601357
2. Higher enantioselectivities in thiourea-catalyzed Michael additions under solvent-free Conditions. Šebesta, R.; Hestericová, M. Tetrahedron, 2014, 70, 901-905. https://www.sciencedirect.com/science/article/pii/S0040402013018838
3. Organocatalyst Efficiency in the Michael Additions of Aldehydes to Nitroalkenes in Water and in a Ball-Mill. Veverková, E.; Poláčková, V.; Liptáková, L.; Kázmerová, E.; Mečiarová, M.; Toma, Š.; Šebesta, R. ChemCatChem 2012, 4, 1013-1018. https://onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201200105

1. Trapping of chiral enolates generated by Lewis acid promoted conjugate addition of Grignard reagents to unreactive Michael acceptors by various electrophiles. Vargová, D.; Perez, J. M.; Harutyunyan, S. R.; Šebesta, R. Chem. Commun. 2019, 55, 11766-11769. https://pubs.rsc.org/en/content/articlelanding/2019/cc/c9cc05041h/unauth#!divAbstract
2. Diastereoselective Pd-Catalyzed CH Arylation of Ferrocenylmethanamines with Arylboronic Acids or Pinacol Esters. Plevová, K.; Mudráková, B.; Rakovský, E.; Šebesta, R. J. Org. Chem. 2019, 84, 7312-7319. https://pubs.acs.org/doi/full/10.1021/acs.joc.9b00953
3. Retro-Brook Rearrangement of Ferrocene-Derived Silyl Ethers. Bariak, V.; Malastová, A.; Almássy, A.; Šebesta, R. Chem. Eur. J. 2015, 21, 13445-13453. https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201501711
4. Asymmetric one-pot conjugate addition of Grignard reagents to α,β-unsaturated compounds followed by reaction with carbenium ions. Drusan, M.; Rakovský, E.; Marek, J.; Šebesta, R. Adv. Synth. Catal. 2015, 357, 1493-1498. https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201500074
5. Enantioselective Michael reaction of acetals with nitroalkenes – an improvement of the oseltamivir synthesis. Tisovský, P.; Peňaška, T.; Mečiarová, M.; Šebesta, R. ACS Sust. Chem. Eng. 2015, 3, 3429-3434. https://pubs.acs.org/doi/abs/10.1021/acssuschemeng.5b01172

Orcid ID: 0000-0002-7975-3608
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• stereoselective reactions